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Yes; he dies in almost every episode in which he appears. He can't permanently die, though, as Rose/Bad Wolf brought him back to life with the power of the time vortex.

There is a large controversy as to whether Captain Jack is the Face of Boe, but if he is, then it is possible for him to ultimately die of old age, as shown in "Gridlock". For more information on the Face of Boe controversy, visit Is Jack Harkness the Face of Boe.